Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivativew
نویسندگان
چکیده
A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies. CANTAT, Thibault, et al. Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative. Chemical Communications, 2008, no. 7, p.
منابع مشابه
Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative.
A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.
متن کاملPOLAROGRAPHIC AND POTENTIOSTATIC REDUCTION OF CARBODIIMIDES: A MECHANISTIC STUDY
The polarographic reduction of aromatic carbodiimides in anhydrous aprotic solvents goes through a carbene intermediate by a diffusion controlled process in two one-electron steps. The first step is the rate-determining step and converts the carbodiirnide to a radical anion (6) that reduces further by a fast one-electron step to a carbene dianion intermediate (7). This abstracts an oxygen, ...
متن کاملElectrochemical Investigation of Antibacterial Laser Dye Compound in 1,2-Dichloroethane at a Platinum Electrode
Diolefinic antibacterial laser dye namely 1,4-Bis[2-(4-Pyridyl) Vinyl] Benzene (4PVB)have been investigated electrochemically using cyclic voltammetry, chronoamperometry, convolution and deconvolution voltammetry combined with digital simulation techniques at a platinum electrode in 0.1 mol / L Tetra Butyl Ammonium Perchlorate (TBAP) in solvent 1,2-dichloroethane. The diolefinic ...
متن کاملBis sulfamic acid functionalized magnetic nanoparticles as a retrievable nanocatalyst for the green synthesis of polyhydroquinolines and tetrahydrobenzopyrans
Synthesis of bis sulfamic acid-grafted on silica-coated nano-Fe3O4 particles (MNPs-TBSA) as a novel core/shell hybrid organic-inorganic magnetic nanostructures, and their performance as a retrievable heterogeneous acidic catalyst is disclosed. The catalytic performance of this novel material was studied for the green synthesis of pharmaceutically valuable polyhydroquinoline and tetrahydrobenzop...
متن کاملTotal Phenolic and Flavonoids Contents, Radical Scavenging Activity and Green Synthesis of Silver Nanoparticles by Laurus nobilis L. Leaves Aqueous Extract
In this project, total phenolic and flavonoid contents of the aqueous extract of Laurus nobilis L. leaves were evaluated by colorimetric methods. These natural products which are found in plants extracts, can be considered as reducing and stabilizing agents in the synthesis of metal nanoparticles. Regarding to high amounts of these compounds in the extract, silver nanoparticles were synthesized...
متن کامل